SYMMETRICAL OR UNSYMMETRIC CLEAVAGE OF THE BRIDGING SYSTEM IN [M(2)(MU-C6F5)(2)(C6F5)(4)](2-)(M(2)=PT-2, PD-2 OR PTPD) WITH 2,2'-BIPYRIDINE OR 1,10-PHENANTHROLINE - MOLECULAR-STRUCTURE OF [PPN](2)[(C6F5)(3)PT(MU-BPY)PT(C6F3)(3)] AND [NBU(4)][PT(C6F5)(3)(PHEN)]

被引：20

作者：

USON, R

FORNIES, J

TOMAS, M

MARTINEZ, F

CASAS, JM

FORTUNO, C

机构：

[1] Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-C.S.I.C.

来源：

INORGANICA CHIMICA ACTA | 1995年 / 235卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; PLATINUM COMPLEXES; PALLADIUM COMPLEXES; PERFLUOROARYL COMPLEXES; BIDENTATE LIGAND COMPLEXES;

D O I：

10.1016/0020-1693(95)90045-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Binuclear M(2) (M = Pt, Pd) complexes with bridging N-N (N-N = bpy) [NBu(4)](2)[M(2)(mu-N-N)(C6F5)(6)], mononuclear Pt complexes with monodentate bpy or phen [NBu(4)][Pt(C6F5)(3)(N-N)] or neutral mononuclear Pt complexes with chelating phen [Pt(C6F5)(2)(N-N)] or Pd complexes with bpy or phen [Pd(C6F5)(2)(N-N)] can be prepared starting from [NBu(4)](2)[M(2)(mu-C6F5)(2)(C6F5)(4)] by adequate choice of solvents and reactions conditions. The crystal structures of [PPN](2)[Pt-2(mu-bpy)(C6F5)(6)] and [NBu(4)][Pt(C6F5)(3)(phen)] have been established by X-ray crystallography.

引用

页码：51 / 60

页数：10

共 19 条

[1] TETRA-N-BUTYLAMMONIUM TRIS(PERFLUORO-PHENYL)(TRIPHENYLPHOSPHINE)PLATINATE(II) [J].

ARA, I ;

TOMAS, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :375-377

[2] CRYSTAL-STRUCTURE OF CIS-CHLOROBIS(TRIETHYLPHOSPHINE)-1,10-PHENANTHROLINEPLATINUM(II) FLUOROBORATE, (PTCL(PET3)2(PHEN)BF4, A COMPLEX CONTAINING MONODENTATE 1,10-PHENANTHROLINE [J].

BUSHNELL, GW ;

DIXON, KR ;

KHAN, MA .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1974, 52 (08) :1367-1376

[3] HETEROBINUCLEAR PTAG COMPOUNDS WITH PLATINUM SILVER BONDS UNSUPPORTED BY COVALENT BRIDGES - MOLECULAR-STRUCTURE OF (C6F5)3(SC4H8)PTAGPPH3 [J].

COTTON, FA ;

FALVELLO, LR ;

USON, R ;

FORNIES, J ;

TOMAS, M ;

CASAS, JM ;

ARA, I .

INORGANIC CHEMISTRY, 1987, 26 (09) :1366-1370

[4] THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(MU-4,4'-DIMETHYL-2,2'-BIPYRIDYL)BIS(PENTACARBONYLCHROMIUM(0))] - THE 1ST STRUCTURAL DETERMINATION OF A COMPLEX CONTAINING A BRIDGING 2,2'-BIPYRIDYL LIGAND [J].

CREAVEN, BS ;

LONG, C ;

HOWIE, RA ;

MCQUILLAN, GP ;

LOW, J .

INORGANICA CHIMICA ACTA, 1989, 157 (02) :151-152

[5] FLUXIONAL BEHAVIOR OF POTENTIALLY BIDENTATE PHENANTHROLINE, BIPYRIDINE, NAPHTHYRIDINE, PYRIDAZINE, AND PHTHALAZINE LIGANDS IN PLATINUM COMPLEXES [J].

DIXON, KR .

INORGANIC CHEMISTRY, 1977, 16 (10) :2618-2624

[6] REACTIVITY OF [PD(CN)(C6F5)(NCME)] (CN = ((DIMETHYLAMINO)METHYL)PHENYL-C2,N, 8-QUINOLYMETHYL-C,N) TOWARD 2,2'-BIPYRIDINE OR 1,10-PHENANTHROLINE - SYNTHESIS AND STRUCTURES OF [(PD(8-MQ)(C6F5))2(MU-BPY)] AND [(C6F5)(8-MQ)PD(MU-8-MQ)PD(C6F5)(PHEN)], DINUCLEAR COMPLEXES CONTAINING UNUSUAL 2,2'-BIPYRIDINE OR UNPRECEDENTED 8-QUINOLYMETHYL-C,N ACTING AS BRIDGING LIGANDS [J].

FORNIES, J ;

NAVARRO, R ;

SICILIA, V ;

TOMAS, M .

INORGANIC CHEMISTRY, 1993, 32 (17) :3675-3681

[7] THE CRYSTAL STRUCTURE OF 2,2'-BIPYRIDINE [J].

MERRITT, LL ;

SCHROEDER, ED .

ACTA CRYSTALLOGRAPHICA, 1956, 9 (09) :801-804

[8] PARST - A SYSTEM OF FORTRAN ROUTINES FOR CALCULATING MOLECULAR-STRUCTURE PARAMETERS FROM RESULTS OF CRYSTAL-STRUCTURE ANALYSES [J].

NARDELLI, M .

COMPUTERS & CHEMISTRY, 1983, 7 (03) :95-98

[9]

Reedijk J., 1987, COMPREHENSIVE COORDI, V2, P73

[10] SYNTHESIS AND REACTIVITY OF BINUCLEAR HOMO-METALLIC OR HETERO-METALLIC COMPLEXES [NBU4]2[MM'(MU-C6F5)2(C6F5)4] (M = M' = PD OR PT, M = PT, M' = PD) WITH BRIDGING PENTAFLUOROPHENYL GROUPS [J].

USON, R ;

FORNIES, J ;

TOMAS, M ;

CASAS, JM ;

NAVARRO, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (01) :169-172

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