EQUILIBRIA IN COMPLEXES OF N-HETEROCYCLIC MOLECULES, .22. THE REACTION OF TRIAQUO(2,4,6-TRI-(2-PYRIDYL)-1,3,5-TRIAZINE) COPPER(II) AND ITS NICKEL(II) AND COBALT(II) ANALOGS WITH WATER AND HYDROXIDE ION

被引：16

作者：

GILLARD, RD ^{[1
]}

WILLIAMS, PA ^{[1
]}

机构：

[1] UNIV WALES UNIV COLL CARDIFF,DEPT INORGAN CHEM,CARDIFF CF1 1XL,S GLAMORGAN,WALES

来源：

TRANSITION METAL CHEMISTRY | 1979年 / 4卷 / 01期

关键词：

D O I：

10.1007/BF00941010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics of the reaction of [Cu(TPT)(H2O)3]2+ and [Ni(TPT)(H2O)3]2+ with H2O have been followed and it has been shown that the formation of covalent hydrates is important in the understanding of these systems. The [Co(TPT)(OH)3]- compound and its Ni analogue are attacked by HO- initially to form pseudo-base species and in, the case of Ni, the ligand then hydrolyses to yield a compound related to the carboximate formed when HO- reacts with [Cu(TPT)(OH)3]-. In this reaction too, the formation of a pseudo-base, involving attack of HO- at the triazine ring in the ligand is significant. © 1979 Verlag Chemie, GmbH.

引用

页码：18 / 23

页数：6

共 12 条

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