STABILIZATION OF THE 1-NAPHTHYLTROPYLIUM ION BY [2.2]PARACYCLOPHANE FIXED AT THE FACE-TO-FACE POSITION TO THE TROPYLIUM RING

被引：13

作者：

KOMATSU, K

TSUJI, R

INOUE, Y

TAKEUCHI, K

机构：

[1] Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University, Sakyo-ku, Kyoto

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 01期

关键词：

ROPYLIUM ION; 2.2]PARACYCLOPHANE; CHARGE-TRANSFER INTERACTION; PKR+; AM1; CALCULATION;

D O I：

10.1016/S0040-4039(00)60067-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title cation, in which [2.2]paracyclophane and the tropylium ring are rigidly fixed at the face-to-face arrangement, was synthesized, and was found to exhibit the highest stability in a series of (8-substituted 1-naphthyl)tropylium ions prepared so far.

引用

页码：99 / 102

页数：4