LATTICE THEORY OF SOLVATION AND DISSOCIATION IN MACROMOLECULAR FLUIDS .1. MEAN-FIELD APPROXIMATION

被引：13

作者：

OLENDER, R ^{[1
]}

NITZAN, A ^{[1
]}

机构：

[1] TEL AVIV UNIV,SACKLER FAC SCI,SCH CHEM,IL-69978 TEL AVIV,ISRAEL

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 01期

关键词：

D O I：

10.1063/1.466935

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper analyzes solvation and association in macromolecular solvents using mean-field theory applied to several lattice-gas models. The thermodynamic functions of solvation and the equilibrium constant for association is calculated in terms of the temperature, pressure, and solvent molecular size. Applications to ion association in polymer electrolytes are discussed and the advantages and flaws of the model are critically analyzed. Exact results for a simple one dimensional model are also obtained and discussed.

引用

页码：705 / 718

页数：14

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