EQUILIBRIA IN COMPLEXES OF N-HETEROCYCLIC MOLECULES .24. REACTION OF NUCLEOPHILES WITH TRIS-(2,2'-BIPYRIMIDINE)IRON(II) ION AND ITS RUTHENIUM(II) ANALOG

被引：15

作者：

GILLARD, RD ^{[1
]}

LANCASHIRE, RJ ^{[1
]}

WILLIAMS, PA ^{[1
]}

机构：

[1] UNIV WALES UNIV COLL CARDIFF,DEPT INORGAN CHEM,CARDIFF CF1 1XL,S GLAMORGAN,WALES

来源：

TRANSITION METAL CHEMISTRY | 1979年 / 4卷 / 02期

关键词：

D O I：

10.1007/BF00618837

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [Fe(bipym)3]2+ and [Ru(bipym)3]2+ with hydroxide ion in aqueous solution have been followed. The [Ru(bipym)3]2+ species undergoes nucleophilic attack at the ligand to yield [Ru(bipym)2(pyrimidine)(OH)]+ and [HCO2]- ion, involving cleavage of one pyrimidyl ring. Intermediates can be observed in the reaction of [Fe(bipym)3]2+ with HO-, N3- and SCN-. The kinetics of the first reaction have been followed and the results are compared with those known for the reactions of [Fe(bipy)3]2+, [Fe(phen)3]2+ and similar compounds. © 1979 Verlag Chemie, Gmbh.

引用

页码：115 / 118

页数：4

共 21 条

[1]

ARCESAGUES JA, J CHEM SOC DA

[2]

BLANDAMER MJ, TRANSITION MET CHEM

[3] SYNTHESIS OF 2,2'-BIPYRIMIDINE FROM 2-BROMOPYRIMIDINE [J].

BLY, DD ;

MELLON, MG .

JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (08) :2945-&

[4] KINETICS OF REACTION OF TRIS(2,2'-BIPYRIDYL)IRON(II) WITH CYANIDE IN AQUEOUS-SOLUTION [J].

BURGESS, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (10) :1061-&

[5] ACID SOLVOLYSIS OF TRIS-(1,10-PHENANTHROLINE)IRON(II) IN DIMETHYLSULFOXIDE - CHLORIDE-ION CATALYSIS, VIA ION-PAIR FORMATION [J].

FARRINGTON, DJ ;

JONES, JG ;

TWIGG, MV .

INORGANICA CHIMICA ACTA, 1977, 25 (02) :L75-L76

[6]

GIL VMS, TRANSITION MET CHEM

[7]

GILLARD R, UNPUBLISHED

[8] EQUILIBRIA IN COMPLEXES OF N-HETEROCYCLIC MOLECULES .13. RACEMIZATION AND DISSOCIATION OF SOME TRIS(1,10-PHENANTHROLINE) AND TRIS(2,2'-BIPYRIDYL)-COMPLEXES OF IRON-(II) AND IRON-(III) [J].

GILLARD, RD ;

KANEMAGUIRE, LAP ;

WILLIAMS, PA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (18) :1792-1797

[9] EQUILIBRIA IN COMPLEXES OF N-HETEROCYCLIC MOLECULES, .9. CIRCULAR-DICHROISM STUDY OF NUCLEOPHILIC-ATTACK AT TRIS-(5-NITRO-1,10-PHENANTHROLINE)RUTHENIUM(II) [J].

GILLARD, RD ;

KANEMAGUIRE, LAP ;

WILLIAMS, PA .

TRANSITION METAL CHEMISTRY, 1977, 2 (01) :12-13

[10] EQUILIBRIA IN COMPLEXES OF N-HETEROCYCLIC MOLECULES .8. REACTION OF TRIS(5-NITRO-1,10-PHENANTHROLINE)RUTHENIUM(II) CATION WITH METHOXIDE AND ETHOXIDE IONS [J].

GILLARD, RD ;

KANEMAGUIRE, LAP ;

WILLIAMS, PA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (10) :1039-1044

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