QUASI-CLASSICAL TRAJECTORY STUDY OF THE LI+CS-2 REACTION

被引：4

作者：

MORAIS, VMF ^{[1
]}

VARANDAS, AJC ^{[1
]}

机构：

[1] UNIV COIMBRA, DEPT QUIM, P-3409 COIMBRA, PORTUGAL

来源：

MOLECULAR PHYSICS | 1995年 / 84卷 / 05期

关键词：

D O I：

10.1080/00268979500100661

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report quasiclassical trajectory calculations for the reaction Li + Cs2 --> LiCs + Li. The influence of the very pronounced mass differences of the colliding partners on the various dynamics attributes is investigated in detail. A remarkable linear dependence of the translational exothermicity as a function of the initial translational energy is observed, and rationalized using a hybrid statistical/stripping-spectator model.

引用

页码：957 / 969

页数：13

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