DIPOLAR NARROWED CARR-PURCELL MEASUREMENT OF ROTATING FRAME SPIN-LATTICE PARAMETERS IN POLYMERS

被引:16
作者
DYBOWSKI, C [1 ]
PEMBLETON, RG [1 ]
机构
[1] IOWA STATE UNIV,AMES LAB,US DOE,AMES,IA 50011
关键词
D O I
10.1063/1.437675
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The use of the dipolar-narrowed Carr-Purcell sequence for measuring the spin-lattice contribution to the linewidth under multiple pulse sequences is demonstrated. The relaxation in polyisoprene is exponential with a time constant, T1y, of the order of T1p for the sample. The relaxation rate depends on pulse spacing in a manner not predicted by assuming an exponential correlation function for the reorientation. © 1979 American Institute of Physics.
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页码:1962 / 1966
页数:5
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