NMR CHEMICAL-SHIFTS IN COPPER-(I) CHALCOGEN COMPOUNDS

被引：11

作者：

BECKER, KD

SCHAFGEN, HP

机构：

[1] Ruhr-Universität Bochum

来源：

SOLID STATE COMMUNICATIONS | 1979年 / 32卷 / 11期

关键词：

D O I：

10.1016/0038-1098(79)90841-X

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

NMR chemical shifts of 63Cu have been determined in the three binary Cu(I) chalcogenides and in six ternary Cu(I) chalcopyrites. In all compounds studied, a decrease of chemical shift is observed with decreasing atomic number of the chalcogen. This downshift is discussed, and accounted for by p-d hybridization of the copper chalcogen bonds. © 1979.

引用

页码：1107 / 1109

页数：3

共 15 条

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