COMPLEXATION OF METHANE AND CHLOROFLUOROCARBONS BY CRYPTOPHANE-A IN ORGANIC SOLUTION

被引：159

作者：

GAREL, L ^{[1
]}

DUTASTA, JP ^{[1
]}

COLLET, A ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER LYON,STEREOCHIM & INTERACT MOLEC,CNRS,UMR 117,F-69364 LYON 07,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 08期

关键词：

D O I：

10.1002/anie.199311691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Equivalent to a supercritical fluid is a description of the- state of the methane molecule in the interior of the host cavity of a cryptophane molecule. The CH4-cryptophane complex (shown on the right) is amazingly stable even at room temperature (K(a) = 130 M-1), and its half-life is 6 mus. The findings of this study shed light on the bonding between neutral guest and neutral host molecules.

引用

页码：1169 / 1171

页数：3

共 16 条

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