THERMAL OXIDATIVE-DEGRADATION OF AN EPOXY-RESIN

被引:59
作者
ROSE, N
LEBRAS, M
DELOBEL, R
COSTES, B
HENRY, Y
机构
[1] Laboratoire de Physiocochimie des Solides, ENSCL, Université des Sciences et Technologies de Lille, F-59652 Villeneuve d'Ascq Cedex
[2] Aérospatiale 12
关键词
D O I
10.1016/0141-3910(93)90226-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study of the thermodegradation of the tetraglycidyl diamino diphenyl methane/diaminodiphenylsulfone system (TGDDM/DDS) defines the differents steps of the carbonization process. It characterizes, in particular, the domain of existence of an expanded carbonaceous structure which is constituted of small domains of turbostratic carbon. Moreover, this present work discusses the role of oxygen in the formation of this structure and shows that there is competition between the carbonization process and the oxidative degradation.
引用
收藏
页码:307 / 316
页数:10
相关论文
共 25 条
[1]  
CAMINO G, 1990, POLY DEG STAB, V28, P24
[2]  
COSTES B, 1989, THESIS LE MANS
[3]  
COSTES B, 1992, CHARGES MINERALES OR
[4]   RAMAN MICROPROBE STUDY OF HEAT-TREATED PITCHES [J].
COTTINET, D ;
COUDERC, P ;
SAINTROMAIN, JL ;
DHAMELINCOURT, P .
CARBON, 1988, 26 (03) :339-344
[5]   ON THE P-31 CHEMICAL-SHIFT ANISOTROPY IN CONDENSED PHOSPHATES [J].
DUNCAN, TM ;
DOUGLASS, DC .
CHEMICAL PHYSICS, 1984, 87 (03) :339-349
[6]   LOW-TEMPERATURE THERMAL-DECOMPOSITION OF AN EPOXY-RESIN [J].
GRAYSON, MA ;
WOLF, CJ .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (08) :1897-1907
[7]  
GRENIERLOUSTALO.MF, 1992, POLYMER, V33
[8]   THE ROLE OF IMPURITIES IN THE MECHANISMS AND KINETICS OF REACTIONS OF EPOXY-RESINS AND THEIR EFFECTS ON FINAL RESIN PROPERTIES [J].
GRENIERLOUSTALOT, MF ;
GRENIER, P .
BRITISH POLYMER JOURNAL, 1990, 22 (04) :303-313
[9]  
KOURTIDES DA, 1975, J FIRE SCI, V6, P373
[10]   MECHANICAL-PROPERTIES AND CHEMISTRY OF CARBONIZATION OF PHENOL FORMALDEHYDE RESIN [J].
LAUSEVIC, Z ;
MARINKOVIC, S .
CARBON, 1986, 24 (05) :575-580