TEMPERATURE DEPENDENCE OF ELECTRICAL AND DIFFUSIONAL MOBILITIES OF 22NA AND 137CS IN MOLTEN LINO3 NANO3 AND RBNO3

被引：14

作者：

KWAK, JCT

KETELAAR, JA

机构：

[1] Laboratory for Electrochemistry, University of Amsterdam, Amsterdam

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 01期

关键词：

D O I：

10.1021/j100721a016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The diffusion coefficients and ionic mobilities of 22Na and 137Cs in molten LiNO3, NaNO3, and CsNO3 are measured by a paper electrophoresis method in the temperature range of about 300-400°. The values of the Arrhenius coefficients and of the preexponential factors are given. The Nernst-Einstein relation between mobility and diffusion coefficient is discussed.

引用

收藏

页码：94 / &

相关论文

共 27 条

[1] SELF-DIFFUSION AND ELECTRICAL CONDUCTANCE MEASUREMENTS ON SOLUTIONS OF CADMIUM IN MOLTEN CADMIUM CHLORIDE [J].

ANGELL, CA ;

TOMLINSON, JW .

DISCUSSIONS OF THE FARADAY SOCIETY, 1961, (32) :237-&

[2] ELECTRO-OSMOSIS AND HYDROGEN-ION TRANSPORT IN CATION-EXCHANGE MEMBRANES [J].

ARNOLD, R ;

SWIFT, DA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1967, 20 (12) :2575-&

[3]

DESPIC A, 1956, DISCUSSIONS FARADAY, P121

[4] SELF-DIFFUSION IN MOLTEN NITRATES [J].

DWORKIN, AS ;

ESCUE, RB ;

VANARTSDALEN, ER .

JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (07) :872-876

[5] ELECTROCHEMICAL PROPERTIES OF IONOGENIC MEMBRANES PREPARED BY THERMAL AND OXIDATIVE DEGRADATION OF POLY(VINYL ALCOHOL) [J].

ELLISON, TM ;

SPENCER, HG .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1963, 1 (12) :707-&

[6] STRUCTURE AND PROPERTIES OF HETEROGENEOUS CATION-EXCHANGE MEMBRANES [J].

HALE, DK ;

MCCAULEY, DJ .

TRANSACTIONS OF THE FARADAY SOCIETY, 1961, 57 (01) :135-&

[7] MEMBRANE POTENTIALS .1. THEORY OF EMF OF CELLS CONTAINING ION-EXCHANGE MEMBRANES [J].

HILLS, GJ ;

LAKSHMINARAYANAIAH, N ;

JACOBS, PWM .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1961, 262 (1308) :246-+

[8] MEMBRANE POTENTIALS .2. MEASUREMENT OF EMF OF CELLS CONTAINING CATION-EXCHANGE MEMBRANE, CROSSED-LINKED POLYMETHACRYLIC ACID [J].

HILLS, GJ ;

JACOBS, PWM ;

LAKSHMINARAYANAIAH, N .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1961, 262 (1308) :257-+

[9] ELECTROMIGRATION AND SELF-DIFFUSION IN IONIC MELTS [J].

HONIG, EP ;

KETELAAR, JA .

TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (517P) :190-&

[10] DIFFUSIONAL AND ELECTRICAL MOBILITIES OF TRACER ALKALI IONS IN ALKALI NITRATES [J].

KETELAAR, JA ;

KWAK, JCT .

JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (04) :1149-&