CONJUGATED ADDITION OF ALKYL DERIVATIVES OF THE 4D METALS AG, PD, RH, RU, CO AND FE TO 2-CYCLOHEXANONE

被引：14

作者：

KAUFFMANN, T

HULSDUNKER, A

MENGES, D

NIENABER, H

RETHMEIER, L

ROBBE, S

SCHERLER, D

SCHRICKEL, J

WINGBERMUHLE, D

机构：

[1] Organisch-Chemisches Institut der Universität Münster, D-4400 Münster

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 11期

关键词：

D O I：

10.1016/0040-4039(90)80014-D

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In situ prepared alkyl derivatives of the 4d metals Ag, Rh (Alk = Me, n-Bu), Pd, Ru (Alk = Me) alkylate 2-cyclohexenone (1) exclusively or preferently in β-position to the keto group. The same was observed by applying Me2Fe, Me3FeLi or the hetero-ate complexes Me2(t-BuO)2FeLi2 and Me2(t-BuO)2CoLi2, whereas Me4FeLi2 methylates 1 at the keto group. © 1990.

引用

页码：1553 / 1556

页数：4

共 11 条

[1]

BISLING M, 1985, THESIS U MUNSTER

[2] ORGANOMANGANESE(II) REAGENTS .11. A STUDY OF THEIR REACTIONS WITH CYCLIC CONJUGATED ENONES - CONJUGATE ADDITION AND REDUCTIVE DIMERIZATION [J].