ELECTRICAL AND MAGNETIC-PROPERTIES AND X-RAY STRUCTURE OF A HIGHLY CONDUCTIVE 4-1 COMPLEX OF TETRACYANOQUINODIMETHANE AND A TETRATHIAFULVALENE DERIVATIVE

被引：168

作者：

BRYCE, MR

MOORE, AJ

HASAN, M

ASHWELL, GJ

FRASER, AT

CLEGG, W

HURSTHOUSE, MB

KARAULOV, AI

机构：

[1] CRANFIELD INST TECHNOL,CTR MOLEC ELECTR,CRANFIELD MK43 0AL,BEDS,ENGLAND

[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[3] UNIV LONDON QUEEN MARY COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Despite strong twisting of the conjugated system, the tetrathiafulvalene homologue 1 reacts with the electron acceptor tetracyanoquinonodimethane to give the dictation 1(2)+. The anthracene moiety is embedded in the 1(2)+ [(TCNQ)4]2-, and the dithiol rings are twisted 86-degrees with respect to the anthracene plane. The 1:4 stoichiometry of the highly conductive salt (sigma-300K = 60 S cm-1) is very unusual for TCNQ complexes.

引用

页码：1450 / 1452

页数：3

共 17 条

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