EXCITED-STATE PROTONATION KINETICS OF COUMARIN-102

被引:33
作者
CAMPILLO, AJ [1 ]
CLARK, JH [1 ]
SHAPIRO, SL [1 ]
WINN, KR [1 ]
WOODBRIDGE, PK [1 ]
机构
[1] UNIV CALIF LOS ALAMOS SCI LAB, LOS ALAMOS, NM 87545 USA
关键词
D O I
10.1016/0009-2614(79)85150-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The rate constant for protonation of the electronically excited state of coumarin 102 in water has been determined to be (1,4 × 0.4) × 1010 mol-1 s-1 using picosecond spectroscopy. The laser pH jump technique is shown to be suitable for rapidly decreasing, as well as increasing, solution pH. © 1979.
引用
收藏
页码:218 / 222
页数:5
相关论文
共 23 条
[1]  
Campillo A. J., 1978, Picosecond phenomena, P319
[2]   PICOSECOND STUDIES OF EXCITED-STATE PROTONATION AND DEPROTONATION KINETICS - LASER PH JUMP [J].
CLARK, JH ;
SHAPIRO, SL ;
CAMPILLO, AJ ;
WINN, KR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (03) :746-748
[3]  
Debye P., 1942, T ELECTROCHEM SOC, V82, P265
[4]  
DEMJASCHKEWITCH AB, 1976, J PHYS CHEM-US, V80, P898
[5]   EVIDENCE FOR EXCIPLEX LASER ACTION IN COUMARIN DYES BY MEASUREMENTS OF STIMULATED FLUORESCENCE [J].
DIENES, A ;
SHANK, CV ;
TROZZOLO, AM .
APPLIED PHYSICS LETTERS, 1970, 17 (05) :189-&
[6]  
Drexhage K. H., 1973, Dye lasers, P144
[8]  
Eisenthal K. B., 1977, Ultrashort light pulses. Picosecond techniques and applications, P275
[9]  
FORSTER T, 1950, Z ELEKTROCHEM, V54, P531
[10]   EXCITED-STATE PROTON-TRANSFER OF A METAL-COMPLEX - DETERMINATION OF ACID DISSOCIATION-CONSTANT FOR A METAL-TO-LIGAND CHARGE-TRANSFER STATE OF A RUTHENIUM(II) COMPLEX [J].
GIORDANO, PJ ;
BOCK, CR ;
WRIGHTON, MS ;
INTERRANTE, LV ;
WILLIAMS, RFX .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (09) :3187-3189