SYNTHESIS OF (-)-BORJATRIOL

被引:11
作者
ABAD, A
AGULLO, C
ARNO, M
CUNAT, AC
ZARAGOZA, RJ
机构
[1] Departamento de Química Orgánica, Universidad de Valencia, Valencia, Dr. Moliner 50
关键词
D O I
10.1021/jo00027a013
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The enantioselective synthesis of (-)-borjatriol ((14R)-8,13-epoxylabdane-7-beta,14,15-triol (1)) from (+)-podocarp-8(14)-en-13-one (2) is described using as a key step the regioselective intramolecular epoxide ring opening of 13.
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页码:50 / 54
页数:5
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