THE VIBRATIONAL-SPECTRA OF N2 IN CLATHRATE-HYDRATES - A NEW HIGH-PRESSURE PHASE-TRANSITION

被引：32

作者：

VANHINSBERG, MGE

SCHEERBOOM, MIM

SCHOUTEN, JA

机构：

[1] Van der Waals-Zeeman Laboratory, University of Amsterdam, 1018 XE Amsterdam

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 01期

关键词：

D O I：

10.1063/1.465751

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

To investigate the interaction between the water framework and a guest molecule in a clathrate hydrate, high-pressure Raman scattering experiments on nitrogen guest molecules have been performed. The pressure dependence of the N2 vibron (s) at room temperature (295 K) has been determined and a new phase transition has been discovered at 0.84 GPa.

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页码：752 / 754

页数：3

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