BIS(5-CARBOMETHOXY-1,3-PHENYLENE)-30-CROWN-4 - A MACROCYCLIC MONOMER OF PREDOMINANTLY HYDROCARBON CHARACTER

被引：7

作者：

GIBSON, HW ^{[1
]}

DELAVIZ, Y ^{[1
]}

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,NSF,BLACKSBURG,VA 24061

来源：

POLYMER | 1994年 / 35卷 / 05期

关键词：

MACROCYCLE; HYDROCARBON; SYNTHESIS;

D O I：

10.1016/0032-3861(94)90962-8

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A general route to 5,5'-difunctionalized bis(m-phenylene) macrocycles (1) is reported. Bis(5-carbomethoxy-1,3-phenylene)-30-crown-4 (1e) has been synthesized in one step from methyl 3,5-dihydroxybenzoate and 1,10-dibromodecane in the presence of sodium hydride in dimethylformamide. This monomer is suitable for synthesis of backbone polymacrocycles of predominantly hydrocarbon character.

引用

页码：1109 / 1110

页数：2

共 8 条

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DELAVIZ, Y ;

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[2] SYNTHESIS OF NEW BIS(M-PHENYLENE)-32-CROWN-10 DERIVATIVES [J].

DELAVIZ, Y ;

GIBSON, HW .

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[3] MACROCYCLIC POLYMERS .2. SYNTHESIS OF POLY(AMIDE CROWN ETHER)S BASED ON BIS(5-CARBOXY-1,3-PHENYLENE)-32-CROWN-10 - NETWORK FORMATION THROUGH THREADING [J].

DELAVIZ, Y ;

GIBSON, HW .

MACROMOLECULES, 1992, 25 (19) :4859-4862

[4] MACROCYCLIC POLYMERS .1. SYNTHESIS OF A POLY(ESTER CROWN) BASED ON BIS(5-CARBOXY-1,3-PHENYLENE)-32-CROWN-10 AND 4,4'-ISOPROPYLIDENEDIPHENOL (BISPHENOL-A) [J].

DELAVIZ, Y ;

GIBSON, HW .

MACROMOLECULES, 1992, 25 (01) :18-20

[5]

DELAVIZ Y, 1991, POLYM COMMUN, V32, P103

[6]

GIBSON HW, 1991, Patent No. 5028721

[7]

GIBSON HW, 1992, Patent No. 5142068

[8]

LAIDLER DA, 1980, CHEM FUNCTIONAL 1 E

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