OXIDATIVE COUPLING OF METHANE ON AN ABO(3) TYPE OXIDE WITH MIXED CONDUCTIVITY

被引：33

作者：

OMATA, K

YAMAZAKI, O

TOMITA, K

FUJIMOTO, K

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 14期

关键词：

D O I：

10.1039/c39940001647

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Substituted SrCoO3-alpha perovskite oxide show high selectivity (>98%) and stable activity for oxidative coupling of methane at 1023 K in the redox system; repeated reaction-oxidation cycles show a high tolerance in a reductive atmosphere; a particular lattice oxide ion is found to be responsible for the selective oxidation of methane.

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页码：1647 / 1648

页数：2

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