CHARGE TRANSFER IN TRANSITION METAL CARBIDES AND RELATED COMPOUNDS STUDIED BY ESCA

被引：561

作者：

RAMQVIST, L

HAMRIN, K

JOHANSSON, G

FAHLMAN, A

NORDLING, C

机构：

[1] The Axel Johnson Institute for Industrial Research, Nynashamn

[2] Institute of Physics, Uppsala University, Uppsala

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1969年 / 30卷 / 07期

关键词：

D O I：

10.1016/0022-3697(69)90252-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron spectroscopic measurements of binding energy shifts of Cl s electrons in Group 4b, 5b and 6b carbides and of core electrons in Ti and V compounds are presented. The results are discussed and compared with X-ray spectroscopic investigations and energy band calculations. It is shown that electrons are transferred from the metal to the carbon atoms when a carbide of this type is formed. © 1969.

引用

页码：1835 / +

页数：1

共 36 条

[1] THE K-AUGER SPECTRUM [J].

ASAAD, WN ;

BURHOP, EHS .

PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1958, 71 (459) :369-382

[2] X-RAY WAVELENGTHS [J].

BEARDEN, JA .

REVIEWS OF MODERN PHYSICS, 1967, 39 (01) :78-&

[3] UBER ELEKTRONENZUSTANDE VON HARTSTOFFEN MIT NATRIUMCHLORIDSTRUKTUR [J].

BILZ, H .

ZEITSCHRIFT FUR PHYSIK, 1958, 153 (03) :338-358

[4]

CONKLIN JB, 1967, B AM PHYS SOC, V12, P416

[5]

CONKLIN JB, 1968, INT J QUANTUM CHEM, V25, P243

[6]

COSTA P, 1964, NUCL METALL S AIME, V10, P3

[7] COHESION IN CUBIC REFRACTORY MONOCARBIDES MONONITRIDES AND MONOXIDES [J].

DENKER, SP .

JOURNAL OF THE LESS-COMMON METALS, 1968, 14 (01) :1-&

[8]

ERN V, 1965, PHYS REV, V137, P1927

[9]

FABIAN DJ, 1968, SOFT XRAY BAND SPECT, P101

[10]

FAHLMAN A, 1966, ARK FYS, V31, P479

← 1 2 3 4 →