HYDROAROMATIC HYDROGENATION-DEHYDROGENATION

被引：11

作者：

GANGWER, T

MACKENZIE, D

CASANO, S

机构：

[1] Department of Energy and Environment, Brookhaven National Laboratory, Upton

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 15期

关键词：

D O I：

10.1021/j100478a017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of the tetralin/1,2-dihydronaphthalene/naphthalene system in the gas phase were studied. The reactions were found to be heterogeneous and followed zero-order rate laws. The rate constants measured at 400°C for initial tetralin conversion to 1,2-dihydronaphthalene plus hydrogen and for initial 1,2-dihydronaphthalene conversion to naphthalene plus hydrogen were 2.3 × 10-14 and 6.3 × 1014 mol/cm2 s, respectively. A heterogeneous mechanistic model is proposed for the system. © 1979 American Chemical Society.

引用

页码：2013 / 2015

页数：3

共 8 条

[1] DEHYDROGENATION OF POLYCYCLIC HYDROAROMATIC COMPOUNDS [J].