STRUCTURE CONFIRMATION OF S-TRANS-TRANS-FARNESYLCYSTEINE IN RHODOTORUCINE-A BY APPLICATION OF SULFONIUM SALT CLEAVAGE REACTION

被引：47

作者：

KAMIYA, Y

SAKURAI, A

TAMURA, S

TAKAHASHI, N

机构：

[1] The Institute of Physical and Chemical Research, Wako-shi, Saitama-ken

来源：

AGRICULTURAL AND BIOLOGICAL CHEMISTRY | 1979年 / 43卷 / 05期

关键词：

D O I：

10.1080/00021369.1979.10863559

中图分类号：

S3 [农学（农艺学）];

学科分类号：

0901 ;

摘要：

Rhodotorucine A is a lipophilic undecapeptide having a novel amino acid, S-farnesylcysteine, at the C-terminus. Sulfonium salt formation of rhodotorucine A and subsequent hydrolysis afforded trans-trans-farnesol, trans-nerolidol and a-bisabolol. Thus, the geometry of the side chain of S-farnesylcysteine was established unambiguously as all trans. The reaction mechanism was also discussed. © 1979 Taylor & Francis Group, LLC.

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页码：1049 / 1053

页数：5

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