The Pronounced Differences in Reactivity of Perfluoro-t-butoxyl and t-Butoxyl Radicals

被引：6

作者：

Davies, Alwyn G. ^{[1
]}

Dennis, Robert W. ^{[1
]}

Roberts, Brian P. ^{[1
]}

Dobbie, Robert C. ^{[2
]}

机构：

[1] Univ Coll London, Christopher Ingold Labs, London WC1H 0AJ, England

[2] Univ Newcastle Upon Tyne, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1974年 / 12期

关键词：

D O I：

10.1039/c39740000468

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perfluoro-t-butoxyl radicals differ from t-butoxyl radicals in that they add to double bonds rather than abstract allylic hydrogens, and abstract hydrogen from the alkyl groups of trialkyl phosphites or trialkyl-boranes in preference to exclusive attack at the metal centre.

引用

页码：468 / U11

页数：2

共 6 条

[1] Davies A. R., UNPUB
[2] ESR STUDY OF OXIDATION OF TRIETHYL PHOSPHITE BY TERT-BUTOXY RADICALS
DAVIES, AG
GRILLER, D
ROBERTS, BP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1971, 10 (10) : 738 - &
[3] HOMOLYTIC ORGANOMETALLIC REACTIONS .3. ELECTRON SPIN RESONANCE STUDY OF HOMOLYTIC TERT-BUTOXYDEALKYLATION OF ORGANOMETALLIC COMPOUNDS - RATE CONSTANTS FOR REACTION AT BORON
DAVIES, AG
GRILLLER, D
ROBERTS, BP
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (09): : 1823 - &
[4] GOULD DE, 1970, J CHEM SOC CHEM COMM, P216
[5] ISOMERIZATION AND ELECTRON SPIN RESONANCE OF ALLYLIC RADICALS
KOCHI, JK
KRUSIC, PJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (25) : 7157 - &
[6] CONFORMATIONAL EFFECTS OF SULFUR, SILICON, GERMANIUM, AND TIN ON ALKYL RADICALS - ELECTRON SPIN RESONANCE STUDY OF BARRIERS TO INTERNAL ROTATION
KRUSIC, PJ
KOCHI, JK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (04) : 846 - &

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