SPECTROSCOPIC STUDIES OF THE SOLUTE SOLVENT INTERACTION IN DYE-DOPED POLYMERS - FREQUENCY-DEPENDENT PRESSURE SHIFTS

被引：21

作者：

REUL, S

RICHTER, W

HAARER, D

机构：

[1] Physikalishes Institut der Universität Bayreuth

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 180卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(91)87106-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The method of hole burning spectroscopy is an excellent means to investigate small shifts and broadenings of quasi-homogeneous optical lines of dye molecules embedded in an amorphous matrix, caused by slight changes in the microscopic matrix environment after applying hydrostatic pressure. We have investigated the pressure-induced line shifts of free-base phthalocyanine in the polymer matrices polyethylene and polystyrene. The experimental data confirm the theoretical prediction of Laird and Skinner pertaining to the frequency dependence of the pressure-induced shifts and the corresponding broadening effects of spectral holes.

引用

页码：1 / 5

页数：5

共 16 条

[1] PHOTOCHEMICAL HOLE BURNING - A SPECTROSCOPIC STUDY OF RELAXATION PROCESSES IN POLYMERS AND GLASSES [J].