A NICKEL MOLYBDENITE CATHODE FOR THE HYDROGEN EVOLUTION REACTION IN ALKALINE MEDIA

被引：22

作者：

ALBERTINI, LB

ANGELO, ACD

GONZALEZ, ER

机构：

[1] Instituto de Fisica e Quimica de Sao Carlos/USP, Sao Carlos, 13560, SP

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1992年 / 22卷 / 09期

关键词：

D O I：

10.1007/BF01023735

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The characteristics and mechanism of the hydrogen evolution reaction on a nickel sulphide electrode incorporating molybdenite particles are described. At 25-degrees-C the overpotential for the reaction is 300 mV lower than that of the mild steel cathodes used in unipolar electrolysers. The material shows good stability under long term operation.

引用

页码：888 / 892

页数：5

共 14 条

[1] MECHANISTIC STUDIES OF THE OXYGEN REACTIONS ON NICO2O4 SPINEL AND THE HYDROGEN EVOLUTION REACTION ON AMORPHOUS NI-CO SULFIDE
ANGELO, ACD
GONZALEZ, ER
AVACA, LA
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1991, 16 (01) : 1 - 7
[2] BICELLI LP, 1973, CHIM IND-MILAN, V55, P792
[3] TRANSITION-METAL SULFIDE CATALYSIS - RELATION OF THE SYNERGIC SYSTEMS TO THE PERIODIC TRENDS IN HYDRODESULFURIZATION
CHIANELLI, RR
PECORARO, TA
HALBERT, TR
PAN, WH
STIEFEL, EI
[J]. JOURNAL OF CATALYSIS, 1984, 86 (01) : 226 - 230
[4] EXPERIMENTAL-EVIDENCE FOR THE POTENTIAL-DEPENDENCE OF ENTROPY OF ACTIVATION IN ELECTROCHEMICAL REACTIONS IN RELATION TO THE TEMPERATURE-DEPENDENCE OF TAFEL SLOPES
CONWAY, BE
TESSIER, DF
WILKINSON, DP
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 199 (02): : 249 - 269
[5] CONWAY BE, 1986, INT J HYDROGEN ENERG, V11, P583
[6] ELECTRODEPOSITS OF IRON AND NICKEL IRON FOR HYDROGEN EVOLUTION IN ALKALINE-SOLUTIONS
DECARVALHO, J
TREMILIOSI-FILHO, G
AVACA, LA
GONZALEZ, ER
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1989, 14 (03) : 161 - 165
[7] DEGIZ MJ, 1989, 175TH P M EL SOC LOS, V89, P1583
[8] ANOMALOUS TEMPERATURE-DEPENDENCE OF THE TAFEL SLOPE
GILEADI, E
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (01) : 117 - 120
[9] THE HYDROGEN EVOLUTION REACTION ON MILD-STEEL AND NICKEL IRON CODEPOSITS IN ALKALINE MEDIA
GONZALEZ, ER
AVACA, LA
CARUBELLI, A
TANAKA, AA
TREMILIOSI-FILHO, G
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1984, 9 (08) : 689 - 693
[10] ADVANCES IN ELECTROCATALYSIS FOR HYDROGEN EVOLUTION IN THE LIGHT OF THE BREWER-ENGEL VALENCE-BOND THEORY
JAKSIC, MM
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1986, 38 (1-2): : 161 - 202

← 1 2 →