ACID-CATALYZED CYCLIZATION OF CEMBRENE AND ISOCEMBROL

被引：19

作者：

DAUBEN, WG ^{[1
]}

HUBBELL, JP ^{[1
]}

OBERHANSLI, P ^{[1
]}

THIESSEN, WE ^{[1
]}

机构：

[1] OAK RIDGE NATL LAB,DIV CHEM,OAK RIDGE,TN 37830

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 05期

关键词：

D O I：

10.1021/jo01319a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The acid-catalyzed ring closure of cembrene, a 14-membered ring diterpene, and its derivatives has been studied. The predominant reaction pathway yields a hydrophenanthrene ring system. Under mild conditions isomeric tricyclic compounds are formed, but under more forcing conditions aromatization of a ring occurs. The detailed mechanisms of these reaction processes have been evaluated. © 1979, American Chemical Society. All rights reserved.

引用

页码：669 / 673

页数：5

共 24 条

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DAUBEN, WG
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PEPPARD, DJ
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DAUBEN, WG
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BROADHURST, MD
MULLER, B
PEPPARD, DJ
PESNELLE, P
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