ASYMMETRIC SILYL NITRONATE CYCLOADDITIONS WITH BORNANE-10,2-SULTAM DERIVATIVES

被引：45

作者：

KIM, BH

LEE, JY

机构：

[1] Department of Chemistry, Center for Biofunctional Molecules, Pohang Institute of Science and Technology, Pohang, 790-600

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 12期

关键词：

OPPOLZERS CHIRAL SULTAM; NITRILE OXIDES; ORGANIC-SYNTHESIS; CYCLO-ADDITIONS; 1,3-DIPOLAR; ROUTE; AUXILIARIES; INDUCTION; REAGENTS; ALPHA;

D O I：

10.1016/S0957-4166(00)80032-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric silyl nitronate cycloadditions with N-acryloyl (2R)-bornane-10,2-sultam, N-acryloyl (2S)-bornane-10,2-sultam, and N-methacryloyl (2R)-bornane-10,2-sultam have been studied. The asymmetric silyl nitronate cycloaddition/elimination methodology provides a general route for the asymmetric synthesis of 2-isoxazolines.

引用

页码：1359 / 1370

页数：12

共 27 条

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