A NEW TEMPLATE ENCAPSULATION STRATEGY FOR LARGER CAVITY METAL-ION CAGES

被引：33

作者：

GEUE, RJ

HOHN, A

RALPH, SF

SARGESON, AM

WILLIS, AC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stereospecific sequential condensation of paraformaldehyde and propionaldehyde with a tripodal bis(triamine)cobalt(III) template rapidly encapsulates the metal, and a subsequent facile reduction of imine functions gives an expanded cavity hexaazabicyclic cage system with unusual structural and chromophore electron properties, complemented by an exceptional stability and relatively fast Co-II/III electron exchange rates.

引用

页码：1513 / 1515

页数：3

共 20 条

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[7] SYNTHESIS AND PROPERTIES OF NOVEL COBALT(III) AND NICKEL(II) COMPLEXES WITH COORDINATED AZETIDINE NITROGENS - CRYSTAL-STRUCTURE OF MER-TRIS(3-(AMINOMETHYL)-3-METHYLAZETIDINE)COBALT(III) CHLORIDE TRIHYDRATE
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