SOLVATION OF LARGE MOLECULES - SOME EXACT RESULTS ON THE DEPENDENCE ON VOLUME AND SURFACE-AREA OF THE SOLUTE

被引：24

作者：

BENNAIM, A

机构：

[1] Department of Physical Chemistry, The Hebrew University of Jerusalem, Jerusalem

来源：

BIOPHYSICAL CHEMISTRY | 1994年 / 51卷 / 2-3期

关键词：

SOLVATION; LARGE MOLECULES; GIBBS AND HELMHOLTZ ENERGIES;

D O I：

10.1016/0301-4622(94)00041-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The solvation Gibbs and Helmholtz energies are evaluated exactly in two model systems. One is a modification of an interstitial model for water, the second is; a non ideal gas mixture within the second virial approximation. In both systems the general form of the solvation Gibb's energy of a large solute s is Delta G*(s) = aV(s) + bA(s), where V-s and A(s) are the volume and surface area of the solute s. We also show that this general form is likely to hold true in any real solution.

引用

页码：203 / 216

页数：14

共 20 条

[1]

Ben-Naim A., 1974, WATER AQUEOUS SOLUTI

[2] SIZE DEPENDENCE OF THE SOLVATION FREE-ENERGIES OF LARGE SOLUTES [J].