PREPARATION AND SUGAR BINDING PROPERTY OF MICROSPHERES HAVING SURFACE-ANCHORED PHENYLBORONIC ACID GROUPS

被引：6

作者：

TSUKAGOSHI, K ^{[1
]}

KAWASAKI, R ^{[1
]}

MAEDA, M ^{[1
]}

TAKAGI, M ^{[1
]}

机构：

[1] KYUSHU UNIV, FAC SCI, DEPT CHEM SCI & TECHNOL, HAKOZAKI 812, FUKUOKA, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 04期

关键词：

D O I：

10.1246/cl.1994.681

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Microspheres having phenylboronic acid groups on the resin surface were successfully prepared by emulsion polymerization of styrene, butyl acrylate, and m-acrylamidophenylboronic acid. The microspheres were swollen in an alkaline aqueous suspension by adding methylethylketone so that phenylboronic acid groups in the resin migrate out to the aqueous-organic interface in their ionized forms. D-Glucose was bound onto the microsphere by complex (ester) formation between phenylboronic acid moiety and cis-diol group of D-Glucose.

引用

页码：681 / 684

页数：4

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