SYNTHESIS OF GLYCOSYL ISOCYANIDES

被引:34
作者
BOULLANGER, P [1 ]
MARMET, D [1 ]
DESCOTES, G [1 ]
机构
[1] UNIV LYON 1,ECOLE SUPER CHIM IND LYON,CHIM ORGAN LAB 2,CNRS,EQUIPE RECH 689,F-69621 VILLEURBANNE,FRANCE
关键词
D O I
10.1016/0040-4020(79)85021-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Substitution of benzylated or methylated glycopyranosyl and furanosyl bromides with silver cyanide gives rise to glycosylisocyanides as main products. The isocyanide structure is ascertained by physical (13C NMR, IR) and by chemical methods (hydrolysis, isomerisation to nitriles). © 1979.
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页码:163 / 167
页数:5
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