ADDITION AND SUBSTITUTION OF SODIUM TO/INTO CERIUM(III) CHLORIDE - NA0.38(NA0.19CE0.81)CL3

被引：20

作者：

KRAMER, K

MEYER, G

机构：

[1] Inst. F. Anorg. Chemie D. Univ, Hannover, D-3000

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1990年 / 589卷 / 10期

关键词：

D O I：

10.1002/zaac.19905890111

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bei der Einwirkung von Natrium auf CeCl3 (verschweißte Ta‐Ampulle, 750°C, 7 d) erhält man Einkristalle der Zusammensetzung Na0,38(2)(Na0,193(3)Ce0,808(3))Cl3 (hexagonal, P63/m, Z = 2; a = 757,07(4); c = 431,56(3) pm, Einkristalldaten). Es liegt eine Substitutions‐(Na0,19Ce0,81) und Additionsvariante (Na0,38) des CeCl3 (UCl3‐Typ) vor. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

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页码：96 / 100

页数：5

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