PERTURBED HYDROGENIC MANIFOLDS STUDIED BY THE RECURSIVE RESIDUE GENERATION METHOD

被引:9
作者
KARLSSON, HO
GOSCINSKI, O
机构
[1] Department of Quantum Chemistry, Uppsala University, Uppsala, S-751 20
关键词
D O I
10.1088/0953-4075/25/23/007
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A method for calculating the perturbation of hydrogenic manifolds, the emerging bound states and resonances, for arbitrary combinations of external fields, is presented. It requires the combined use of complex dilation, an orthonormal Laguerre basis e(-lambdar) L(k)2l+2 (lambdar) rather than the non-orthogonal Sturmians e(-lambdar) L(k)2l+1 (lambdar), and the recursive residue generation method (RRGM) version of the Lanczos algorithm. Generalized eigenvalue problems are avoided. Furthermore, direct computation of the residues of resolvents, transition amplitudes and sum rules is achieved, Comparison with other methods and with previous calculations, suitable for one perturbation at a time, indicates that high accuracy is achieved separately both for the 1s Stark resonance and for the 1s Zeeman effect. Accurate results for the 1s Stark-Zeeman resonance, for various combinations of fields, are given.
引用
收藏
页码:5015 / 5028
页数:14
相关论文
共 56 条
[1]   RESONANCES IN THE STARK-EFFECT AND STRONGLY ASYMPTOTIC APPROXIMANTS [J].
BENASSI, L ;
GRECCHI, V .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1980, 13 (05) :911-930
[2]  
Bethe H. A., 1957, QUANTUM MECH ONEAND, DOI DOI 10.1007/978-3-662-12869-5
[3]   CONTINUUM ORBITALS, COMPLEX SCALING PROBLEM, AND EXTENDED VIRIAL THEOREM [J].
BRANDAS, E ;
FROELICH, P .
PHYSICAL REVIEW A, 1977, 16 (06) :2207-2210
[4]  
BRANDAS E, 1989, RESONANCES
[5]  
BRAUN PA, 1984, ZH EKSP TEOR FIZ, V59, P38
[6]   DILATATION TRANSFORMATION AND STARK-ZEEMAN EFFECT [J].
CHU, SI .
CHEMICAL PHYSICS LETTERS, 1978, 58 (03) :462-466
[7]   THE QUADRATIC ZEEMAN EFFECT IN HYDROGEN RYDBERG SERIES - APPLICATION OF STURMIAN FUNCTIONS [J].
CLARK, CW ;
TAYLOR, KT .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1982, 15 (08) :1175-1193
[8]  
Cullum J. K., 1985, LANCZOS ALGORITHMS L, V1
[9]   HYDROGEN-ATOM IN A UNIFORM ELECTRIC-FIELD [J].
DAMBURG, RJ ;
KOLOSOV, VV .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1976, 9 (18) :3149-3157
[10]   QUANTUM CHAOS AND STATISTICAL PROPERTIES OF ENERGY-LEVELS - NUMERICAL STUDY OF THE HYDROGEN-ATOM IN A MAGNETIC-FIELD [J].
DELANDE, D ;
GAY, JC .
PHYSICAL REVIEW LETTERS, 1986, 57 (16) :2006-2009