REGIOSELECTIVE SYNTHESIS OF CALIXCROWNS DERIVED FROM P-TERT-BUTYLCALIX[5]ARENE

被引：53

作者：

KRAFT, D ^{[1
]}

ARNECKE, R ^{[1
]}

BOHMER, V ^{[1
]}

VOGT, W ^{[1
]}

机构：

[1] UNIV MAINZ,INST ORGAN CHEM,JJ BECHER WEG 34 SB1,W-6500 MAINZ,GERMANY

来源：

TETRAHEDRON | 1993年 / 49卷 / 27期

关键词：

D O I：

10.1016/S0040-4020(01)87186-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkylation of p-tert-butylcalix[5]arene with oligoethylene glycol-ditosylates in the presence of CsF affords the 1,3-bridged calix[5]crowns la-c in 51 to 72% yield. In the case of hexaethylene glycol the isomeric 1,2-bridged calix[5]crown-7 2c was obtained additionally. The calixcrowns were further modified by alkylation of the remaining hydroxyl groups.

引用

页码：6019 / 6024

页数：6

共 21 条

[1] SYNTHESIS, AND X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF A NOVEL MACROBICYCLIC LIGAND - CROWNED PARA-TERT-BUTYL-CALIX[4]ARENE [J].

ALFIERI, C ;

DRADI, E ;

POCHINI, A ;

UNGARO, R ;

ANDREETTI, GD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (19) :1075-1077

[2] SELECTIVE 1,2-FUNCTIONALIZATION OF CALIX[4]ARENES AT THE LOWER RIM - SYNTHESIS OF A NEW TYPE OF BIS-CALIXCROWN ETHER [J].

ARDUINI, A ;

CASNATI, A ;

DODI, L ;

POCHINI, A ;

UNGARO, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (22) :1597-1598

[3] SYNTHESIS, RAPID RESOLUTION, AND DETERMINATION OF ABSOLUTE-CONFIGURATION OF RACEMIC 2,2'-BINAPHTHYLDIYL CROWN ETHERS AND ANALOGS VIA BETA-CYCLODEXTRIN COMPLEXATION [J].

ARMSTRONG, DW ;

WARD, TJ ;

CZECH, A ;

CZECH, BP ;

BARTSCH, RA .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (26) :5556-5559

[4]

ARNAUD F, UNPUB

[5] SYNTHESIS AND COMPLEXING PROPERTIES OF A DOUBLE-CALIX[4]ARENE CROWN-ETHER [J].

ASFARI, Z ;

ABIDI, R ;

ARNAUD, F ;

VICENS, J .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1992, 13 (02) :163-169

[6]

ASFARI Z, 1992, POL J CHEM, V66, P709

[7] THE BARIUM(II) COMPLEX OF P-TERT-BUTYLCALIX[4]ARENE-CROWN-5 - A NOVEL NUCLEOPHILIC CATALYST WITH TRANSACYLASE ACTIVITY [J].

CACCIAPAGLIA, R ;

CASNATI, A ;

MANDOLINI, L ;

UNGARO, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10956-10958

[8] CONFORMATIONAL FREEZING OF PARA-TERT-BUTYLCALIX[6]ARENE IN THE CONE STRUCTURE BY SELECTIVE FUNCTIONALIZATION AT THE LOWER RIM - SYNTHESIS OF NEW PREORGANIZED LIGANDS [J].

CASNATI, A ;

MINARI, P ;

POCHINI, A ;

UNGARO, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (19) :1413-1414

[9] CESIUM FLUORIDE ASSISTED SYNTHESIS OF MACROCYCLIC POLYETHERS WITH AROMATIC SUBUNITS [J].

CZECH, BP ;

CZECH, A ;

BARTSCH, RA .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1985, 22 (05) :1297-1300

[10] KINETICALLY STABLE COMPLEXES OF ALKALI CATIONS WITH RIGIDIFIED CALIX[4]ARENES - SYNTHESIS, X-RAY STRUCTURES, AND COMPLEXATION OF CALIXCROWNS AND CALIXSPHERANDS [J].

DIJKSTRA, PJ ;

BRUNINK, JAJ ;

BUGGE, KE ;

REINHOUDT, DN ;

HARKEMA, S ;

UNGARO, R ;

UGOZZOLI, F ;

GHIDINI, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) :7567-7575

← 1 2 3 →