OXIDATIVE HOMOLYSIS OF THE SUPEROXOPENTAAQUACHROMIUM(III) ION

被引：9

作者：

BAKAC, A

ESPENSON, JH

JANNI, JA

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000315

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polypyridine complexes of Ru-III and Fe-II react with [CT(H2O)(5)O-2](2+) to yield [Cr(H2O)(6)](3+) and O-2 in the first reported case of chemically induced oxidative homolysis of a superoxo metal complex.

引用

页码：315 / 315

页数：1

共 17 条

[1] ELECTRON-TRANSFER VERSUS ENERGY-TRANSFER IN THE REACTIONS OF 2ECR(BPY)3(3+) WITH ORGANOCHROMIUM AND ORGANOCOBALT COMPLEXES [J].

BAKAC, A ;

ESPENSON, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) :3453-3457

[2] REACTIONS OF THE SUPEROXOCHROMIUM(III) ION WITH TRANSITION-METAL COMPLEXES [J].

BRYNILDSON, ME ;

BAKAC, A ;

ESPENSON, JH .

INORGANIC CHEMISTRY, 1988, 27 (15) :2592-2595

[3] EVIDENCE FOR A BOND HOMOLYSIS PATHWAY FOR O2 RELEASE IN THE DECOMPOSITION OF THE SUPEROXOCHROMIUM(III) ION CRO22+ [J].

BRYNILDSON, ME ;

BAKAC, A ;

ESPENSON, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (15) :4579-4583

[4] ELECTROCHEMICALLY INDUCED RELEASE OF DIOXYGEN FROM A COBALT(II) COMPLEX [J].

CAMERON, JH ;

MORGAN, PC ;

TURNER, SC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (22) :1617-1619

[5] ELECTROCHEMICALLY CONTROLLED DISSOCIATION OF DIOXYGEN FROM A MU-PEROXO COBALT(III) DIMER [J].

CAMERON, JH ;

TURNER, SC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (23) :3285-3289

[6] NOVEL ORGANOMETALLIC ANIONS GENERATED BY ELECTROCHEMICAL REVERSIBLE REDUCTION [J].

COSTA, G ;

PUXEDDU, A ;

REISENHO.E .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (17) :993-&

[7] SYNTHETIC OXYGEN CARRIERS RELATED TO BIOLOGICAL-SYSTEMS [J].

JONES, RD ;

SUMMERVILLE, DA ;

BASOLO, F .

CHEMICAL REVIEWS, 1979, 79 (02) :139-179

[8]

KALYANASUNDARAM K, 1982, COORDIN CHEM REV, V46, P161

[9] ELECTROCHEMISTRY OF VITAMIN-B12 .3. ONE-ELECTRON INTERMEDIATES IN REDUCTION OF METHYLCOBALAMIN AND METHYLCOBINAMIDE [J].

LEXA, D ;

SAVEANT, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (10) :3220-3222

[10] MECHANISM OF QUENCHING OF EMISSION OF SUBSTITUTED POLYPYRIDINERUTHENIUM(II) COMPLEXES BY IRON(III), CHROMIUM(III), AND EUROPIUM(III) IONS [J].

LIN, CT ;

BOTTCHER, W ;

CHOU, M ;

CREUTZ, C ;

SUTIN, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (21) :6536-6544

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