SYNTHESIS AND MAGNETIC-PROPERTIES OF FE7C3 PARTICLES WITH HIGH SATURATION MAGNETIZATION

被引:35
作者
TAJIMA, S
HIRANO, S
机构
[1] Department of Applied Chemistry, Nagoya University, Chikusa-ku, Nagoya, 464-01, Furo-cho
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1990年 / 29卷 / 04期
关键词
Barium-containing Fe[!sub]3[!/sub]O[!sub]4[!/sub; Carbon monoxide; Coercivity; Fe[!sub]5[!/sub]C[!sub]2[!/sub; Fe[!sub]7[!/sub]C[!sub]3[!/sub; Magnetic recording media; Ratio of residual magnetization to saturation magnetization; Saturation magnetization;
D O I
10.1143/JJAP.29.662
中图分类号
O59 [应用物理学];
学科分类号
摘要
The formation behavior and magnetic properties of Fe7C3 particles were investigated under atmospheric pressure. The starting material of barium-containing iron oxide was carbureted with CO by heat treatment. Fe7C3 particles were formed in the reaction temperature range of 300–375°C along with a small amount of Fe5C2 particles. Fe7C3 content in the product increased with the increase in the partial pressure of CO and the decrease in the reaction temperature. DTA-TG analysis revealed that the product contained about 5–10 wt% free carbon. The saturation magnetization of the product was about 110 emu/g regardless of the reaction conditions. The coercivity and the ratio of the residual magnetization to the saturation magnetization increased with the increase of the Fe7C3 content in the product. © 1990 The Japan Society of Applied Physics.
引用
收藏
页码:662 / 668
页数:7
相关论文
共 12 条
[1]   A NEW IRON CARBIDE IN HYDROCARBON SYNTHESIS CATALYSTS [J].
ECKSTROM, HC ;
ADCOCK, WA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (02) :1042-1043
[2]  
HANSEN M, 1958, CONSTITUTION BINARY, P353
[3]  
HIRANO S, IN PRESS J MATER SCI
[4]  
HIRANO S, 1990, IN PRESS J JPN SOC P, V30
[5]   SATURATION MAGNETIZATIONS OF IRON CARBIDES [J].
HOFER, LJE ;
COHN, EM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (07) :1576-1582
[6]  
MANES M, 1952, J AM CHEM SOC, V20, P6207
[7]  
NAKA S, 1984, J MATER SCI, V19, P259, DOI 10.1007/BF02403133
[8]  
NAKA S, 1981, 1980 P INT C FERR JA, P929
[9]  
PAUL MW, 1989, J AM CERAM SOC, V72, P110
[10]   STUDY OF THE CARBURIZATION OF AN IRON CATALYST DURING THE FISCHER-TROPSCH SYNTHESIS - INFLUENCE ON ITS CATALYTIC ACTIVITY [J].
PIJOLAT, M ;
PERRICHON, V ;
BUSSIERE, P .
JOURNAL OF CATALYSIS, 1987, 107 (01) :82-91