THE COORDINATION OF PI-CONJUGATED BIDENTATE LIGANDS

被引：14

作者：

CEULEMANS, A

VANQUICKENBORNE, LG

机构：

[1] Chemistry Department, University of Leuven, Leuven

来源：

PURE AND APPLIED CHEMISTRY | 1990年 / 62卷 / 06期

关键词：

D O I：

10.1351/pac199062061081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Double bonding in chelated metal complexes gives rise to specific electronic effects on the metal d-orbitals. It is shown how these interactions can be incorporated in a ligand field model. Special emphasis is placed on the symmetry characteristics of the resulting hamiltonian. Specific predictions of this model with regard to the trigonal splitting in chiral trischelates and to the orthorhombic field in planar bischelates are confronted with the most recent experimental data. © 1990 IUPAC

引用

页码：1081 / 1086

页数：6

共 13 条

[1]

ATANASOV MA, 1987, THEOR CHIM ACTA, V77, P59

[2]

CEULEMANS A, 1985, INORG CHEM, V24, P1153, DOI 10.1021/ic00202a008

[3] UNUSUAL LIGAND-FIELD EFFECTS IN SQUARE-PLANAR COBALT(II) COMPLEXES OF QUADRIDENTATE SCHIFF-BASES [J].