THE STEREOCHEMICAL COURSE OF EXOCYCLIC DISPLACEMENT-REACTIONS OF A 5-RING PHOSPHINATE ESTER

被引：4

作者：

CULLIS, PM

KAYE, AD

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期

关键词：

D O I：

10.1039/c39920000346

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereochemical course of the exocyclic displacement reaction of a five-ring phosphinate (1-methoxy-3-methylphospholan-1-oxide) has been shown to proceed with inversion of configuration, which rules out a pathway involving a single pseudorotation step and suggests a direct in-line displacement with the ring diequatorial in the pentacoordinate intermediate or transition state.

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页码：346 / 348

页数：3

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