ELECTROCHEMICAL POLYMERIZATION OF SEVERAL SALEN-TYPE COMPLEXES - KINETIC-STUDIES IN THE MICROSECOND TIME RANGE

被引：52

作者：

AUDEBERT, P ^{[1
]}

HAPIOT, P ^{[1
]}

CAPDEVIELLE, P ^{[1
]}

MAUMY, M ^{[1
]}

机构：

[1] CNRS, ECOLE SUPER PHYS CHIM IND, RECH ORGAN LAB, F-75231 PARIS 05, FRANCE

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 338卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(92)80428-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The first stages of the electrochemical polymerization of several salen-type complexes were studied by fast cyclic voltammetry on an ultramicroelectrode. In several cases, it was possible to observe the first electrogenerated intermediate and to measure its formal potential. The polymerization process was found to be very fast and to occur in the 10 microsecond time range or faster.

引用

页码：269 / 278

页数：10

共 20 条

[1] KINETIC-ANALYSIS OF REVERSIBLE ELECTRODIMERIZATION REACTIONS BY THE COMBINED USE OF DOUBLE POTENTIAL STEP CHRONOAMPEROMETRY AND LINEAR SWEEP VOLTAMMETRY - APPLICATION TO THE REDUCTION OF 9-CYANOANTHRACENE [J].

AMATORE, C ;

GARREAU, D ;

HAMMI, M ;

PINSON, J ;

SAVEANT, JM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 184 (01) :1-24

[2] NANOSECOND TIME RESOLVED CYCLIC VOLTAMMETRY - DIRECT OBSERVATION OF ELECTROGENERATED INTERMEDIATES WITH BIMOLECULAR DIFFUSION CONTROLLED DECAY USING SCAN RATES IN THE MEGAVOLT PER 2ND RANGE [J].

AMATORE, CA ;

JUTAND, A ;

PFLUGER, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 218 (1-2) :361-365

[3] IDENTIFICATION OF THE 1ST STEPS OF THE ELECTROCHEMICAL POLYMERIZATION OF PYRROLES BY MEANS OF FAST POTENTIAL STEP TECHNIQUES [J].

ANDRIEUX, CP ;

AUDEBERT, P ;

HAPIOT, P ;

SAVEANT, JM .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (24) :10158-10164

[4] FAST KINETICS BY MEANS OF DIRECT AND INDIRECT ELECTROCHEMICAL TECHNIQUES [J].

ANDRIEUX, CP ;

HAPIOT, P ;

SAVEANT, JM .

CHEMICAL REVIEWS, 1990, 90 (05) :723-738

[5] FAST SWEEP CYCLIC VOLTAMMETRY AT ULTRA-MICROELECTRODES - EVALUATION OF THE METHOD FOR FAST ELECTRON-TRANSFER KINETIC MEASUREMENTS [J].

ANDRIEUX, CP ;

GARREAU, D ;

HAPIOT, P ;

PINSON, J ;

SAVEANT, JM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 243 (02) :321-335

[6] ULTRAMICROELECTRODES FOR FAST ELECTROCHEMICAL KINETICS [J].

ANDRIEUX, CP ;

HAPIOT, P ;

SAVEANT, JM .

ELECTROANALYSIS, 1990, 2 (03) :183-193

[7] OBSERVATION OF THE CATION RADICALS OF PYRROLE AND OF SOME SUBSTITUTED PYRROLES IN FAST-SCAN CYCLIC VOLTAMMETRY - STANDARD POTENTIALS AND LIFETIMES [J].

ANDRIEUX, CP ;

AUDEBERT, P ;

HAPIOT, P ;

SAVEANT, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) :2439-2440

[8] FAST SCAN RATE CYCLIC VOLTAMMETRY FOR CONDUCTING POLYMERS ELECTROPOLYMERIZED ON ULTRAMICROELECTRODES [J].

ANDRIEUX, CP ;

AUDEBERT, P ;

HAPIOT, P ;

NECHTSCHEIN, M ;

ODIN, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 305 (01) :153-162

[9]

AUDEBERT P, 1991, NEW J CHEM, V15, P235

[10]

AUDEBERT P, 1991, SYNTHETIC MET, V41, P3049

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