NEW ORGANOTIN(IV) DERIVATIVES OF 1-PHENYL-1H-TETRAZOLE-5-THIOL - CRYSTAL AND MOLECULAR-STRUCTURE OF (1)INFINITY[BZ3SNSCN4PH] - A POLYMER BUILT THROUGH SECONDARY INTERMOLECULAR SN...N BONDS

被引：35

作者：

CEAOLIVARES, R

SANDOVAL, OJ

ESPINOSAPEREZ, G

SILVESTRU, C

机构：

[1] Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Coyoacán, 04510 México, D.F.

来源：

POLYHEDRON | 1994年 / 13卷 / 19期

关键词：

D O I：

10.1016/S0277-5387(00)83441-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Di- and triorganotin(IV) derivatives of 1-phenyl-1H-tetrazole-5-thiol, RnSn(SCN4Ph)4-n (R = Me, Bz; n = 2, 3), were prepared by reacting the corresponding organotin chlorides with the ammonium salt of the thiotetrazolato anion. The title compounds were characterized by means of IR and H-1, C-13 and Sn-119 NMR spectroscopy. The molecular structure of Bz3SnSCN4Ph was investigated using X-ray diffractometry. Data on a redetermination of the crystal and molecular structures of n-Bu2Sn(SCN4Ph)2 are also included, and a comparative discussion of the two structures is presented.

引用

页码：2809 / 2818

页数：10

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