PALLADIUM CATALYSTS IN NATURAL-PRODUCTS SYNTHESIS

被引：19

作者：

TSUJI, J

机构：

[1] Tokyo Institute of Technology, Meguro

来源：

PURE AND APPLIED CHEMISTRY | 1979年 / 51卷 / 06期

关键词：

D O I：

10.1351/pac197951061235

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two important palladium catalyzed reactions, namely oxidation of olefins to methyl ketones with PdCl2/CuCl/O2 system, and telomerization of butadiene with nucleophiles catalyzed by Pd (OAc)2/PPh3 are used in key steps of natural products synthesis. Syntheses of Matsutake alcohol, lipoic acid, diplodialide, lasiodiplodin, zearalenone, 12-acetoxy-1, 3-dodecadiene, ci-scivetone, recifeiolide, royal jelly acid, 2, 15-hexadecanedione are described. © IUPAC

引用

收藏

页码：1235 / 1241

页数：7

相关论文

共 25 条

[1]

BYROM NT, 1976, CHEM COMMUN, P216

[2] IMPROVED PROCEDURES FOR CONVERTING HIGHER ALPHA-OLEFINS TO METHYL KETONES WITH PALLADIUM CHLORIDE [J].

CLEMENT, WH ;

SELWITZ, CM .

JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (01) :241-&

[3]

Ishida T., 1975, CHEM COMMUN, P209

[4] OXIDATIONS OF OLEFINS WITH ALCOHOLIC PALLADIUM(II) SALTS [J].

LLOYD, WG ;

LUBEROFF, BJ .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (12) :3949-&

[5]

MANDAI T, TETRAHEDRON

[6] NEW AND HIGHLY EFFECTIVE ALDOL SYNTHESIS [J].

MARUOKA, K ;

HASHIMOTO, S ;

KITAGAWA, Y ;

YAMAMOTO, H ;

NOZAKI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (23) :7705-7707

[7] ORGANIC SYNTHESIS BY MEANS OF NOBLE-METAL COMPOUNDS .51. PALLADIUM-CATALYZED ADDITION OF BUTADIENE TO NITROALKANES [J].

MITSUYASU, T ;

TSUJI, J .

TETRAHEDRON, 1974, 30 (07) :831-834

[8] ADDITION OF LITHIUM ALUMINUM-HYDRIDE TO OLEFINS CATALYZED BY ZIRCONIUM TETRACHLORIDE - CONVENIENT ROUTE TO ALKANES AND 1-HALOALKANES FROM 1-ALKENES [J].

SATO, F ;

SATO, S ;

SATO, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 122 (02) :C25-C27

[9] REACTIONS OF LITHIUM ALUMINUM-HYDRIDE WITH NONCONJUGATED DIOLEFINS - SELECTIVE REDUCTIONS OF DIOLEFINS AND SELECTIVE PREPARATIONS OF HALOOLEFINS FROM DIOLEFINS [J].

SATO, F ;

SATO, S ;

SATO, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 131 (02) :C26-C28

[10]

Smidt J., 1962, ANGEW CHEM INT EDIT, V1, P80, DOI DOI 10.1002/ANIE.196200801