ELECTROCHEMICAL INVESTIGATION OF THE NATURAL FLOTABILITY OF CHALCOPYRITE

被引:172
作者
GARDNER, JR
WOODS, R
机构
[1] CSIRO Division of Mineral Chemistry, Port Melbourne
关键词
D O I
10.1016/0301-7516(79)90028-0
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The flotation of chalcopyrite particles was investigated using a modified Hallimond tube cell, in which the potential at the mineral-solution interface was controlled potentiostatically. Previous reports that this mineral displays natural flotability at oxidizing potentials and non-flotability at reducing potentials have been confirmed. Anodic oxidation of the mineral surface is responsible for the change from a hydrophilic to a hydrophobic condition. Linear potential sweep voltammetry has identified the products of the anodic reaction as CuS, Fe(OH)3 and S. The presence of sulphur on the mineral surface is considered to be the critical factor in rendering chalcopyrite flotable. © 1979.
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页码:1 / 16
页数:16
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  • [1] Bates, Determination of pH, pp. 458-483, (1964)
  • [2] Chander, Fuerstenau, Effect of potential on the flotation and wetting behaviour of chalcocite and copper, Trans. A.I.M.E., 258, pp. 284-285, (1975)
  • [3] Eadington, Study of oxidation layers on surfaces of chalcopyrite by use of Auger electron spectroscopy, Trans. Inst. Min. Metal., 86, pp. C186-C189, (1977)
  • [4] Finkelstein, Allison, Lovell, Stewart, Natural and induced hydrophobicity in sulphide mineral systems, Advances in Interfacial Phenomena of Particulate/Solution/Gas Systems, 71, pp. 165-175, (1975)
  • [5] Gardner, Woods, The use of a particulate bed electrode for the electrochemical investigation of metal and sulphide flotation, Australian Journal of Chemistry, 26, pp. 1635-1644, (1973)
  • [6] Gardner, Woods, An electrochemical investigation of contact angle and of flotation in the presence of alkylxanthates I Platinum and gold surfaces, Australian Journal of Chemistry, 27, pp. 2139-2148, (1974)
  • [7] Gardner, Woods, An electrochemical investigation of contact angle and of flotation in the presence of alkylxanthates II Galena and pyrite surfaces, Australian Journal of Chemistry, 30, pp. 981-991, (1977)
  • [8] Gaudin, Miaw, Spedden, Native flotability and crystal structure, Proc. 2nd Int. Congr. of Surface Activity, 3, pp. 202-219, (1957)
  • [9] Hall, Stewart, The crystal structure refinement of chalcopyrite, CuFeS<sub>2</sub>, Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 29 B, pp. 579-585, (1973)
  • [10] Heyes, Trahar, The natural flotability of chalcopyrite, Int. J. Miner. Process., 4, pp. 317-344, (1977)