CATALYTIC EPOXIDATION OF PROPYLENE WITH TERT-BUTYL HYDROPEROXIDE IN THE PRESENCE OF MODIFIED CARBOXY CATION-EXCHANGE RESIN AMBERLITE IRC-50

被引：40

作者：

IVANOV, S

BOEVA, R

TANIELYAN, S

机构：

[1] Institute of Organic Chemistry, Bulgarian Academy of Sciences, Sofia

来源：

JOURNAL OF CATALYSIS | 1979年 / 56卷 / 02期

关键词：

D O I：

10.1016/0021-9517(79)90101-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic epoxidation of propylene with tert-butyl hydroperoxide in the presence of a modified weakly acidic cation-exchange resin, Amberlite IRC-50, is carried out. The order of reaction with respect to the hydroperoxide and the catalyst is studied, as well as the effect of temperature and the solvent, and an assumption is made for the formation of an intermediate complex between the olefine, the catalyst, and the hydroperoxide. © 1979.

引用

页码：150 / 159

页数：10

共 17 条

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[8] METAL ACETYLACETONATE CATALYZED EPOXIDATION OFOLEFINS WITH T-BUTYL HYDROPEROXIDE
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BRILL, WF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (06) : 2074 - &
[9] CATALYTIC EPOXIDATION OF PROPYLENE WITH TERT-BUTYL PEROXIDE IN PRESENCE OF MOLYBDENUM COMPLEXES ON POLYMER CARRIERS
IVANOV, S
BOEVA, R
TANIELYAN, S
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 1976, 5 (03): : 297 - 301
[10] JUREWICZ AT, 1978, AUG AM CHEM SOC M CH

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