OPTICALLY-ACTIVE BIPYRIDINES IN ASYMMETRIC CATALYSIS

被引：215

作者：

BOLM, C ^{[1
]}

ZEHNDER, M ^{[1
]}

BUR, D ^{[1
]}

机构：

[1] UNIV BASEL,INST ANORGAN CHEM,CH-4056 BASEL,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 02期

关键词：

D O I：

10.1002/anie.199002051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bipyridine derivative 1 is a very promising catalyst. It was obtained by asymmetric syn‐thesis, is optically active, and accelerates the addition of diethylzinc to aldehydes. This re‐action affords good yields of product and proceeds with high asymmetric induction (up to 97% ee). (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：205 / 207

页数：3

共 29 条

[1] OPTICALLY-ACTIVE NITROGEN LIGANDS .3. ENANTIOFACE-DISCRIMINATING TRANSFER HYDROGENATION OF ACETOPHENONE CATALYZED BY RHODIUM(I) COMPLEXES WITH CHIRAL 2-(2'-PYRIDYL)PYRIDINES
BOTTEGHI, C
CHELUCCI, G
CHESSA, G
DELOGU, G
GLADIALI, S
SOCCOLINI, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 304 (1-2) : 217 - 225
[2] HIGHLY EFFICIENT ASYMMETRIC REDUCTION OF ALPHA-TERTIARY ALKYL KETONES WITH DIISOPINOCAMPHEYLCHLOROBORANE
BROWN, HC
CHANDRASEKHARAN, J
RAMACHANDRAN, PV
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (17) : 3394 - 3396
[3] BRUNNER H, 1988, SYNTHESIS-STUTTGART, P645
[4] ASYMMETRIC CATALYSIS .45. ENANTIOSELECTIVE HYDROSILYLATION OF KETONES WITH [RH(COD)CL]2/PYRIDINYLOXAZOLINE CATALYSTS
BRUNNER, H
OBERMANN, U
[J]. CHEMISCHE BERICHTE-RECUEIL, 1989, 122 (03): : 499 - 507
[5] NUCLEAR MAGNETIC RESONANCE SPECTRA OF 2,2'-BIPYRIDYL
CASTELLANO, S
GUNTHER, H
EBERSOLE, S
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (12) : 4166 - +
[6] DIISOPINOCAMPHEYLCHLOROBORANE, A REMARKABLY EFFICIENT CHIRAL REDUCING AGENT FOR AROMATIC PROCHIRAL KETONES
CHANDRASEKHARAN, J
RAMACHANDRAN, PV
BROWN, HC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (25) : 5446 - 5448
[7] TRANSITION-METAL-MEDIATED PHOSPHORUS CARBON BOND-CLEAVAGE AND ITS RELEVANCE TO HOMOGENEOUS CATALYST DEACTIVATION
GARROU, PE
[J]. CHEMICAL REVIEWS, 1985, 85 (03) : 171 - 185
[8] GLADIALI S, 1988, APPLIED ORGANOMET CH, V2, P227
[9] DIOXOMOLYBDENUM(VI)-SUBSTITUTED 2,6-PYRIDINEDIMETHANOL COMPLEXES - NEW 5-COORDINATE SPECIES
HAWKINS, JM
DEWAN, JC
SHARPLESS, KB
[J]. INORGANIC CHEMISTRY, 1986, 25 (09) : 1501 - 1503
[10] ASYMMETRIC EPOXIDATION MODELS - AN ALKYL HYDROPEROXIDE DEPENDENT CHANGE IN MECHANISM
HAWKINS, JM
SHARPLESS, KB
[J]. TETRAHEDRON LETTERS, 1987, 28 (25) : 2825 - 2828

← 1 2 3 →