HEXAMOLYBDENUM CLUSTER WITH ONE TELLURIDE AND 7 CHLORIDE CAPPING LIGANDS

被引：10

作者：

EBIHARA, M

IMAI, T

KAWAMURA, T

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194013466

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetraethylammonium hepta-mu(3)-chloro-mu(3)-telluro-hexachlorohexamolybdate, (Et(4)N)(3)[(Mo6Cl6Te)Cl-6], has an octahedral hexamolybdenum cluster core whose faces are capped by seven Cl atoms and one Te atom. The capping telluride is disordered in the crystal. The average Mo-Mo distance is not much different from those in [(Mo(6)Cl(7)Z)Cl-6](3-) (Z = S, Se).

引用

页码：1743 / 1745

页数：3

共 6 条

[1] SYNTHESIS, STRUCTURE, AND PROPERTIES OF OXIDIZED HEXAMOLYBDENUM CLUSTERS [(MO6X7Y)X'6]2- (X = X' = CL, BR, Y = S, SE) [J].