A 3-DIMENSIONAL FRAMEWORK ALUMINO-PHOSPHATE (CH3NH3)+[AL3P3O13H]-

被引：33

作者：

CHIPPINDALE, AM

POWELL, AV

JONES, RH

THOMAS, JM

CHEETHAM, AK

HUO, QS

XU, RR

机构：

[1] HERIOT WATT UNIV, DEPT CHEM, EDINBURGH EH14 4AS, MIDLOTHIAN, SCOTLAND

[2] UNIV KEELE, DEPT CHEM, KEELE ST5 5BG, STAFFS, ENGLAND

[3] UCL ROYAL INST GREAT BRITAIN, DAVY FARADAY RES LAB, LONDON W1X 4BS, ENGLAND

[4] JILIN UNIV, DEPT CHEM, CHANGCHUN, PEOPLES R CHINA

[5] UNIV CALIF SANTA BARBARA, DEPT MAT, SANTA BARBARA, CA 93106 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194003537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, previously designated as JDF-2 [Gai-Boyes, Thomas, Wright, Jones, Natarajan, Chen & Xu (1992). J. Phys. Chem. 96, 8206-8209], is an aluminium phosphate (AlPO) with a three-dimensional framework structure consisting of three types of PO4 tetrahedral unit linked to three crystallographically distinct Al atoms. One of the Al atoms is tetrahedrally coordinated (as AlO4) while the remaining two have distorted trigonal bipyramidal coordination and are linked through a common O atom to form O4Al-OH-AlO4 units. These units are relatively rare features in AlPO frameworks as the Al- and P-containing polyhedra are usually linked in a strictly alternating manner.

引用

页码：1537 / 1540

页数：4

共 12 条

[1] CRYSTAL-STRUCTURE OF ALPO4-21, A FRAMEWORK ALUMINOPHOSPHATE CONTAINING TETRAHEDRAL PHOSPHORUS AND BOTH TETRAHEDRAL AND TRIGONAL-BIPYRAMIDAL ALUMINUM IN 3-RING, 4-RING, 5-RING, AND 8-RING [J].