GAS CHROMATOGRAPHY-MASS SPECTROMETRY OF A SERIES OF FATTY-ACID METHYL-ESTER CHLOROHYDRINS AND THEIR TRIMETHYLSILYL DERIVATIVES

被引：12

作者：

STARTIN, JR

GILBERT, J

MCWEENY, DJ

机构：

[1] Ministry of Agriculture Fisheries and Food, Food Science Division, Norwich, NR4 7UA, Colney Lane

来源：

JOURNAL OF CHROMATOGRAPHY | 1978年 / 152卷 / 02期

关键词：

D O I：

10.1016/S0021-9673(00)85086-4

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The reaction is reported between hdyrogen chloride and a series of epoxy fatty acid methyl esters leading to the formation of mixtures of isomeric chlorohydrins. Although these chlorohydrins decomposed during gas chromatography to form oxo-compounds, their trimethylsilyl ether derivatives were found to be sufficienty stable for analysis. The mass spectra are reported for the parent chlorohydrins obtained on a direct insertion probe, and for the trimethylsilyl derivatives obtained by combined gas chromatography-mass spectrometry. © 1978.

引用

页码：495 / 499

页数：5