A SIMULATION STUDY OF THE UT-3 THERMOCHEMICAL HYDROGEN-PRODUCTION PROCESS

被引：26

作者：

YOSHIDA, K

KAMEYAMA, H

AOCHI, T

NOBUE, M

AIHARA, M

AMIR, R

KONDO, H

SATO, T

TADOKORO, Y

YAMAGUCHI, T

SAKAI, N

机构：

[1] TOKYO UNIV AGR & TECHNOL,DEPT CHEM ENGN,KOGANEI,TOKYO 184,JAPAN

[2] JAPAN ATOM ENERGY RES INST,CHIYODA KU,TOKYO 105,JAPAN

[3] TOKYO ENGN CORP,DIV PROC ENGN,TOKYO,TOKYO 100,JAPAN

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 1990年 / 15卷 / 03期

关键词：

D O I：

10.1016/0360-3199(90)90087-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of kinetic and simulation studies of four reactions consisting of the UT-3 cycle was made aiming at industrialization of this process. This cycle is given by 1CaBr2(s)+H2O(g)→CaO(s)+2HBr(g)2CaO(s)+Br2(g)→CaBr(s)+1{plus 45 degree rule}202(g)3Fe3O4(s)+8HBr(g)→3FeBr2(s)+4H2O(g)+Br2(g)43FeBr2(s)+4H2O(g)→Fe3O4(s)+6HBr(g)+H2(g). This paper deals with rate expressions of these gas-solid reactions experimentally measured. Then, a simulation model for four fixed-bed reactors, in which four reactions are performed, and the calculation results are described. Also, the concept of process simulator is explained. © 1990.

引用

页码：171 / 178

页数：8

共 6 条

[1] PROCESS SIMULATION OF MASCOT PLANT USING THE UT-3 THERMOCHEMICAL CYCLE FOR HYDROGEN-PRODUCTION [J].