JAHN-TELLER SPLITTINGS IN OPTICAL ABSORPTION SPECTRA OF DIVALENT IRON IN CADMIUM-CHLORIDE-TYPE CRYSTALS

被引:24
作者
FREEMAN, TE
JONES, GD
机构
[1] Department of Physics, University of Canterbury, Christchurch
来源
PHYSICAL REVIEW | 1969年 / 182卷 / 02期
关键词
D O I
10.1103/PhysRev.182.411
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Measurements of the Jahn-Teller splittings of the T2g5(D5)→Eg5(D5) optical transition of divalent iron in the near infrared are reported for CdCl2, CdBr2, MgCl2, and MnCl2 crystals containing about 15% divalent iron and for ferrous chloride. The variation of the magnitude of the observed splittings with temperature for the various host crystals is discussed and compared with theoretical predictions. © 1969 The American Physical Society.
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页码:411 / &
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