CIRCULAR DICHROISM .37. SYNTHESIS AND CIRCULAR DICHROISM OF BETA-AXIAL METHYLADAMANTANONE

被引:56
作者
SNATZKE, G
EHRIG, B
KLEIN, H
机构
[1] Organisch-chemisches Institut der Universität Bonn, Bonn
关键词
D O I
10.1016/S0040-4020(01)83066-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The two enantiomeric 2a-methyl-adamantan-4-one have been synthesized by different methods. The contributions to the Cotton effect of an axial Me group in β-position of a cyclohexanone is practically zero, though a pronounced fine structure is found in unpolar solvents. © 1969.
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页码:5601 / &
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