INTERACTION OF OXYGEN WITH POLYTHIOZYL, (SN)X, ELECTRODES

被引：6

作者：

CZERWINSKI, A

VOULGAROPOULUS, AN

JOHNSON, JF

MARK, HB

机构：

[1] Department of Chemistry, University of Cincinnati, Cincinnati, Ohio

来源：

ANALYTICAL LETTERS PART A-CHEMICAL ANALYSIS | 1979年 / 12卷 / 10期

关键词：

Adsorption; background currents; Electrodes; Oxygen; Polythiozyl; Surface Functional Groups;

D O I：

10.1080/00032717908082536

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Studies of the background currents for polythioxyl electrodes in 1 N H2SO4supporting electrolyte shows that oxygen strongly chemisorbs on both parallel and perpendicular surfaces. On fresh surfaces the principle product on anodic breakdown is oxygen but on prolonged cycling surface hydroxides of (SN)xare the major surface functional groups at anodic breakdown. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：1089 / 1094

页数：6

共 8 条

[1] BEADOUIE S, 1978, CR ACAD SC PARIS C, V286, P217
[2] SURFACE MODIFICATION OF (SN)X ELECTRODES - SURFACE INTERACTION OF METAL-CATIONS
MARK, HB
NOWAK, RJ
KUTNER, W
JOHNSON, JF
MACDIARMID, AG
[J]. BIOELECTROCHEMISTRY AND BIOENERGETICS, 1978, 5 (01): : 215 - 222
[3] SYNTHESIS AND STRUCTURE OF METALLIC POLYMERIC SULFUR NITRIDE, (SN)X, AND ITS PRECURSOR, DISULFUR DINITRIDE, S2N2
MIKULSKI, CM
RUSSO, PJ
SARAN, MS
MACDIARMID, AG
GARITO, AF
HEEGER, AJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (22) : 6358 - 6363
[4] MIKULSKI CM, 1976, INORG CHEM, V15, P2963
[5] BEHAVIOR OF POLYMERIC SULFUR NITRIDE, (SN), ELECTRODES IN AQUEOUS-MEDIA
NOWAK, RJ
KUTNER, W
MARK, HB
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (02) : 232 - 240
[6] NOWAK RJ, UNPUBLISHED
[7] NOWAK RJ, 1977, JCS CHEM COMM, V9
[8] VOULGAROPOULOS AN, 1978, JCS CHEM COMM

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